Preheat your oven to 350 degrees Fahrenheit.
Sift the flour, cocoa powder, baking soda, baking powder and salt into a mixing bowl.
⅔ Cup All Purpose Flour, ½ Cup Cocoa Powder, ⅔ teaspoon Baking Soda, ⅓ teaspoon Baking Powder, ½ teaspoon Salt
In a separate bowl whisk together the buttermilk, oil, brown sugar, egg and orange zest until smooth. Pour the wet ingredients into the dry and mix until fully incorporated.
⅓ Cup Buttermilk, 2 tablespoon Neutral Oil, 3 Tablespoons Orange zest, 1 Large Egg, ⅔ Cup Brown Sugar
Add the melted dark chocolate and coffee – then mix to combine.
¼ Cup Dark Chocolate, ⅓ Cup Espresso
Pour batter into a greased 8-inch cake pan and bake for 25-30 minutes. Make sure to check that the cake is fully baked by testing with a toothpick before removing it from the oven and allowing it to cool completely.